Esterification (shown below) is a reaction converting a carboxylic acid to its ester. It involves only the carbonyl carbon. Esterification of $(-)$ lactic acid with methanol yields $(+)$ methyl lactate. Assuming that there are no side reactions,what is true about this reaction?

  • A
    An $S_N2$ process has occurred,inverting the absolute configuration of the chiral center
  • B
    An $S_N1$ reaction at the chiral center has inverted the optical rotation
  • C
    $A$ diastereomer has been produced; diastereomers have different physical properties including optical rotation
  • D
    Optical rotation is not directly related to absolute configuration,so the change in sign of rotation is merely a coincidence

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Similar Questions

Statement $(A)$: Carboxylic acid can be obtained by the reaction of $R-C \equiv N$ with $H_3O^+$ under mild reaction conditions.
Statement $(B)$: Hydrolysis of $R-C \equiv N$ in alkaline aqueous medium gives $R-COONa$ and $NH_3$ as products.
The correct answer is:

$CH_3COOH \xrightarrow{LiAlH_4} A$
$A + CH_3COOH \xrightarrow{H_3O^+} B + H_2O$
In the above reactions,'$A$' and '$B$' respectively are:

The following transformation can be carried out in three steps. The reagents required for these three steps in their correct order are:

Find out the major products $A$ and $B$ from the following reaction sequence.

An organic compound $(A)$ (molecular formula $C_{8}H_{16}O_{2}$) was hydrolysed with dilute sulphuric acid to give a carboxylic acid $(B)$ and an alcohol $(C)$. Oxidation of $(C)$ with chromic acid produced $(B)$. $(C)$ on dehydration gives but$-1-$ene. Write equations for the reactions involved.

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